Solid-state and aggregation-induced emission of novel bicyclic and tricyclic difluoroboron heterocycles
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F24%3A39921765" target="_blank" >RIV/00216275:25310/24:39921765 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2024/ma/d4ma00653d" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2024/ma/d4ma00653d</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d4ma00653d" target="_blank" >10.1039/d4ma00653d</a>
Alternative languages
Result language
angličtina
Original language name
Solid-state and aggregation-induced emission of novel bicyclic and tricyclic difluoroboron heterocycles
Original language description
Six novel bicyclic and tricyclic difluoroboron NBN and OBN heterocycles were designed here in the quest for novel luminogenic molecular architectures because of their strong application potential as active layers in optoelectronics and as responsive units in sensing. They were prepared and then characterized with spectral (UV-vis, NMR, and luminescence) and electrochemical methods, and assessed via theoretical and X-ray investigations. Most of the compounds are non-emissive in solution, but luminescent in the solid state (red or yellow-green luminescence), and they are AIE active, offering excellent contrast for sensing schemes. Keeping this in view, two compounds were successfully embedded in Pluronic-silica nanoparticles (PluS NPs), coupling the AIEgenic properties of these compounds with the exceptional colloidal stability and functional surface of this type of nanostructure. Here, six novel bicyclic and tricyclic difluoroboron NBN and OBN heterocycles were designed for their strong potential as active layers in optoelectronics and responsive units in sensing applications.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Materials advances
ISSN
2633-5409
e-ISSN
2633-5409
Volume of the periodical
5
Issue of the periodical within the volume
19
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
7721-7728
UT code for WoS article
001307975000001
EID of the result in the Scopus database
2-s2.0-85204901731