Epoxidation of Camelina sativa oil methyl esters as a second-generation biofuel with thermodynamic calculations
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F24%3A39922231" target="_blank" >RIV/00216275:25310/24:39922231 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0960148124007389?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0960148124007389?via%3Dihub</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.renene.2024.120670" target="_blank" >10.1016/j.renene.2024.120670</a>
Alternative languages
Result language
angličtina
Original language name
Epoxidation of Camelina sativa oil methyl esters as a second-generation biofuel with thermodynamic calculations
Original language description
The epoxidation of methyl esters found in Camelina sativa (CS) non-edible oil - largely containing unsaturated fatty acids - was performed. Epoxides are known to be used in biopolymer formation and CO2 capture. This study distinctively demonstrates epoxidation process through a combination of statistical methods and quantum chemical thermodynamic calculations. Esters produced along with glycerol during transesterification of vegetable oils can be used efficiently through epoxidation. Epoxidation products synthesized at various reaction conditions (including oil refinement) were analyzed through gas chromatography with mass spectrometry. According to the statistical analysis, the reaction time and temperature had the highest effect on the composition of products and oil refining is unnecessary. Moreover, iodine values (ester conversion) were determined without the use of chemicals through Raman spectroscopy. The study findings indicate CS epoxidation to be an environmentfriendly process.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Renewable Energy
ISSN
0960-1481
e-ISSN
1879-0682
Volume of the periodical
228
Issue of the periodical within the volume
July 2024
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
120670
UT code for WoS article
001267125800001
EID of the result in the Scopus database
2-s2.0-85193525743