Gypsum dehydration to Alpha-gypsum in mixed chloride solutions

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26110%2F12%3APU96620" target="_blank" >RIV/00216305:26110/12:PU96620 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Gypsum dehydration to Alpha-gypsum in mixed chloride solutions
Original language description
Brno University of Technology solves in the long term the problem of alpha gypsum preparation by dehydrating the gypsum in the solution of chloride salts. This study verified that alpha-gypsum can be trouble free prepared by gypsum dehydration in solution of a number chloride salts, among others CaCl2, MgCl2 or NaCl. In the same time it was found that owing to the different electro-chemical behavior of Potassium ions, the by heat conditioned reaction of gypsum with the KCl solution the dehydration doesnt take place, but a partial substitution of Potassium ions by Calcium ions takes place. The product of this reaction is the mineral görgeyit, K2SO4.5CaSO4.H2O.This important problem was solved by reduction of the extremely electrochemical high mobility of Potassium ions by the method of the mixed chloride solution with Potassium and Sodium ions, the mobility of which is in comparison with the preceding only one third. Samples of hemihydrate in the solution of mixed salts were prepared an
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
JN - Civil engineering
OECD FORD branch
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Project
<a href="/en/project/FR-TI2%2F653" target="_blank" >FR-TI2/653: Complex building programme based on high-valueable gypsum binder from secondary raw materials</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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