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Interstitial nitrogen enhances corrosion resistance of an equiatomic CoCrNi medium-entropy alloy in sulfuric acid solution

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26210%2F20%3APU138321" target="_blank" >RIV/00216305:26210/20:PU138321 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S1044580320323408" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1044580320323408</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.matchar.2020.110869" target="_blank" >10.1016/j.matchar.2020.110869</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Interstitial nitrogen enhances corrosion resistance of an equiatomic CoCrNi medium-entropy alloy in sulfuric acid solution

  • Original language description

    The corrosion resistance of the equiatomic CoCrNi medium-entropy alloy (MEA) and its 0.5 atomic % nitrogen alloyed variant in 0.1 M H2SO4 solution was investigated and compared with that of the 316 L stainless steel as a reference material. All of the investigated materials showed single-phase face centered cubic (FCC) microstructures, and nitrogen was fully dissolved in the solid solution structure of the CoCrNi MEA. Both the nitrogen-free and nitrogen-doped MEAs showed significantly higher corrosion resistance (lower corrosion currents and rates) than the 316 L steel. Compared to the nitrogen-free CoCrNi, the interstitial nitrogen dissolved in solid solution causes a significant improvement in the pitting corrosion resistance of the CoCrNiN. Under the same testing condition, pitting corrosion was not observed in the CoCrNiN alloy, while the CoCrNi MEA and 316 L steel showed distinct pitting cavities. The better anti-corrosion performance of the CoCrNiN compared to that of the CoCrNi is correlated with a higher fraction of chromium oxide in the passive films.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20501 - Materials engineering

Result continuities

  • Project

    <a href="/en/project/GA19-22016S" target="_blank" >GA19-22016S: Dual phase alloys with extraordinary performance arising from nanotwinning</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    MATERIALS CHARACTERIZATION

  • ISSN

    1044-5803

  • e-ISSN

    1873-4189

  • Volume of the periodical

    172

  • Issue of the periodical within the volume

    110869

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    10

  • Pages from-to

    1-10

  • UT code for WoS article

    000620424600004

  • EID of the result in the Scopus database

    2-s2.0-85098981990