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Cleaner production of biodiesel from novel non-edible seed oil (Carthamus lanatus L.) via highly reactive and recyclable green nano CoWO3@rGO composite in context of green energy adaptation

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26210%2F23%3APU150287" target="_blank" >RIV/00216305:26210/23:PU150287 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0016236122030897?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0016236122030897?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.fuel.2022.126265" target="_blank" >10.1016/j.fuel.2022.126265</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Cleaner production of biodiesel from novel non-edible seed oil (Carthamus lanatus L.) via highly reactive and recyclable green nano CoWO3@rGO composite in context of green energy adaptation

  • Original language description

    Sustainable and cheaper intercession coupled with green technologies could be the feasible and finest approach for addressing the solicitous snags like energy crises, greenhouse gas emissions and fossil fuel depletions globally. Biodiesel appeared as a feasible substitute to achieve net zero emissions globally. Biodiesel produced from waste, toxic and non-edible oil seeds is clean, cheaper and capable for producing greener energy which ultimately contributed positively in boosting bio-economy (close circular economy). In the present study, the potential of Carthamus lanatus L. seed oil (CSO) as novel, non-edible and waste feedstock was investigated for producing biodiesel using cobalt tungstate loaded reduced graphene oxide (CoWO3@rGO) as novel, green and recyclable catalysts. The catalyst (CoWO3@rGO) was synthesized via Hummers method followed by characterizations by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR) and energy dispersive X-ray analysis (EDX). Optimize biodiesel yield (99.7 wt%) was achieved with optimum re-action conditions of 0.8 wt% catalyst, oil to methanol molar ratio of 1:12 and temperature 65 degrees C for 2 h reaction time. The optimized Carthamus lanatus L. biodiesel (CBD) yield was also predicted by drawing 3D surface plots with response surface methodology (Box-Behnken design). The synthesized CBD was also characterized using latest techniques of nuclear magnetic resonance (NMR) (1H and 13C), Gas Chromatography/Mass spectroscopy (GC-MS) and FT-IR. The green nanocomposite exhibits excellent reusability of seven times without significant drop in its reactivity during transesterification process. Fuel properties of fatty acid methyl ester complied with biodiesel international standards EN 14214, China GB/T 20828-2007 and ASTM D 6751. Ultimately, biodiesel produced from wild, uncultivated and non-edible CSO can be commendably used to engender and adopt a greener and sustainable energy

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10400 - Chemical sciences

Result continuities

  • Project

    <a href="/en/project/EF15_003%2F0000456" target="_blank" >EF15_003/0000456: Sustainable Process Integration Laboratory (SPIL)</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    FUEL

  • ISSN

    0016-2361

  • e-ISSN

    1873-7153

  • Volume of the periodical

    332

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    20

  • Pages from-to

    „“-„“

  • UT code for WoS article

    000886098700001

  • EID of the result in the Scopus database

    2-s2.0-85140923953