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Modeling of magnetic properties of A2BB′O6 compounds using ab initio and Monte Carlo methods

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26210%2F26%3A0199219" target="_blank" >RIV/00216305:26210/26:0199219 - isvavai.cz</a>

  • Result on the web

    <a href="https://ceramics.onlinelibrary.wiley.com/doi/10.1111/jace.70204" target="_blank" >https://ceramics.onlinelibrary.wiley.com/doi/10.1111/jace.70204</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1111/jace.70204" target="_blank" >10.1111/jace.70204</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Modeling of magnetic properties of A2BB′O6 compounds using ab initio and Monte Carlo methods

  • Original language description

    Ab initio and Monte Carlo simulations are employed to estimate isotropic exchange interactions and Curie temperature of A2BB ' O6 oxides (A alkaline-earth metal or transition metal and B, B ' transition metals). The dominant (B-B') interactions are antiferromagnetic (AFM) between the first and second nearest neighbors (NN), and these interactions strengthen as the magnetic moments of B and B' increase. Third and fourth NN interactions (B-B or B '-B ') are always weaker than the others. Although B '-B ' interactions induce magnetic frustration if they are AFM, the ground state is always ferrimagnetic. The Curie temperature range spans from 290 K for Sr2FeOsO6 to 640 K for Be2FeOsO6. Our study reveals that, in the search for a desired high Curie temperature of A2BB ' O6 oxides, an A cation should be as small as possible, and B, B ' magnetic moments should be as large as possible.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20504 - Ceramics

Result continuities

  • Project

    <a href="/en/project/GA23-06856S" target="_blank" >GA23-06856S: Compositionally complex ceramic oxides: Ab initio design and experimental verification</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2025

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of the American Ceramic Society

  • ISSN

    0002-7820

  • e-ISSN

    1551-2916

  • Volume of the periodical

    108

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    1-9

  • UT code for WoS article

    001561393500001

  • EID of the result in the Scopus database

    2-s2.0-105014892039