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Investigation of the effect of mechanical pressure on the performance of negative lead accumulator electrodes during PSoC operation

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26220%2F12%3APU94282" target="_blank" >RIV/00216305:26220/12:PU94282 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Investigation of the effect of mechanical pressure on the performance of negative lead accumulator electrodes during PSoC operation

  • Original language description

    In the present work, our attention has been focused on the desired prevention of irreversible sulphation of negative test electrodes during cycling under simulated high-rate HEV duty. To this end, the negative active material was doped with carbon and, for comparison, with titanium dioxide as a nonconducting powdered additive, and the negative as well as positive electrodes were subjected to a defined pressure. Accelerated cycling revealed that electrodes doped with carbon in laboratory VRLA cells perform, in the first run, better than those doped with TiO2 since they reached about 30,000 cycles regardless of the applied pressure. However, the electrode performances were almost equalized in the second run. Mechanical pressure of 4 N.cm-2 has a pronounced favourable effect on the cycle life of negative electrodes with expanders. Higher pressures are not recommended. Electrodes doped with carbon but without standard expanders are capable of long-life cycling at elevated pressures around

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/ED0014%2F01%2F01" target="_blank" >ED0014/01/01: Research and Technology Centre of Renewable Energy Sources</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Power Sources

  • ISSN

    0378-7753

  • e-ISSN

  • Volume of the periodical

    1

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    37-44

  • UT code for WoS article

    000302666800007

  • EID of the result in the Scopus database