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UV-vis Investigation of Nickel Diimine Catalyst Systems Activated by Various Chlorinated Alkylaluminiums

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F09%3APU79094" target="_blank" >RIV/00216305:26310/09:PU79094 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    UV-vis Investigation of Nickel Diimine Catalyst Systems Activated by Various Chlorinated Alkylaluminiums

  • Original language description

    Stability of growing centers of hex-1-ene polymerization catalyzed by diimine nickel complex activated by diethylaluminium chloride (DEAC), ethylaluminium dichloride (EADC), dimethylaluminium chloride (DMAC) and methylaluminium dichloride (MADC) was studied by means of UV-vis spectrophotometry. It was found that monochlorinated alkylaluminiums were more efficient in stabilization catalytic system without presence of monomer than monoalkylated alkylaluminiums.

  • Czech name

    Studium stability diiminnikelnatého katalytického systému aktivovaného různými alkylaluminii pomocí technik UV-vis spektrofotometrie

  • Czech description

    Pomocí UV-vis spektrofotometrie byla studována stabilita růstových center polymerace hex-1-enu katalyzované diiminnikelnatým katalyzátorem aktivovaným diethylaluminiumchloridem (DEAC, ethylaluminiumdichloridem (EADC), dimethylaluminiumchloridem (DMAC) amethylaluminiumdichloridem (MADC). Byl zjištěno, že monochlorovaná alkylaluminia jsou ve stabilizaci katalytického systému bez přítomnosti monomeru efektivnější než monoalkylovaná alkylaluminia.

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Workshop Book

  • ISBN

    978-80-968433-6-7

  • ISSN

  • e-ISSN

  • Number of pages

    1

  • Pages from-to

  • Publisher name

    Slovak Academy of Sciences

  • Place of publication

    Bratislava

  • Event location

    Krompachy

  • Event date

    Feb 2, 2009

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article