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Utilization of flow-through electrochemical coulometry in study of dissociation ability of humic acids

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F14%3APU110587" target="_blank" >RIV/00216305:26310/14:PU110587 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Utilization of flow-through electrochemical coulometry in study of dissociation ability of humic acids

  • Original language description

    Humic acids are operationally defined as the fraction of humic substances which is not soluble under acidic conditions. This does not mean, however, that their solid particles easily dissolve in water. Experimental results suggest that the dissolving ofsolid humic acids in an aqueous environment is more complex than the conventional solubility behaviour of sparingly soluble solids. In this work, the pKa value of the dissolved humic acid fraction is calculated on the basis of results of flow-through electrochemical coulometry in combination with potentiometry. While the potentiometric pH-measurement is used for determination of dissociated functional groups of humic acids, whole amount of dissolved humic acids can be measured using the coulometry. Theaim of this work is to characterize the dissociation behaviour of selected humic samples by means of dissociation constants using these methods. It is shown that dissociation degree is influenced by content of dissolved humic acids. The o

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LO1211" target="_blank" >LO1211: Materials Research Centre at FCH BUT- Sustainability and Development</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů