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Characterization of pH-fractionated humic acids with respect to their dissociation behaviour

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F16%3APU117309" target="_blank" >RIV/00216305:26310/16:PU117309 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s11356-015-5932-2" target="_blank" >http://dx.doi.org/10.1007/s11356-015-5932-2</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s11356-015-5932-2" target="_blank" >10.1007/s11356-015-5932-2</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Characterization of pH-fractionated humic acids with respect to their dissociation behaviour

  • Original language description

    Humic acids were divided into several fractions using buffer solutions as extraction agents with different pH values. Two methods of fractionation were used. The first one was subsequent dissolution of bulk humic acids in buffers adjusted to different pH. The second one was sequential dissolution in buffers with increasing pH values. Experimental data were compared with hypothesis of partial solubility of humic acids in aqueous solutions. Behaviour of humic fractions obtained by sequential dissolution, original bulk sample and residual fractions obtained by subsequent dissolution at pH 10 and 12 agrees with the hypothesis. Results demonstrated that regardless the common mechanism, solubility and dissociation degree of various humic fractions may be very different and can be estimated using parameters of the model based on the proposed mechanism. Presented results suggest that dissolving of solid humic acids in water environment is more complex than conventional solubility behaviour of sparingly soluble solids.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

    <a href="/en/project/LO1211" target="_blank" >LO1211: Materials Research Centre at FCH BUT- Sustainability and Development</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH

  • ISSN

    0944-1344

  • e-ISSN

    1614-7499

  • Volume of the periodical

    23

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    10

  • Pages from-to

    7722-7731

  • UT code for WoS article

    000374994600064

  • EID of the result in the Scopus database

    2-s2.0-84953379016