Properties in Aqueous Solution of Homo- and Copolymers of Vinylphosphonic Acid Derivatives Obtained by UV-Curing
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F17%3APU123441" target="_blank" >RIV/00216305:26310/17:PU123441 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s13233-017-5026-8" target="_blank" >http://dx.doi.org/10.1007/s13233-017-5026-8</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s13233-017-5026-8" target="_blank" >10.1007/s13233-017-5026-8</a>
Alternative languages
Result language
angličtina
Original language name
Properties in Aqueous Solution of Homo- and Copolymers of Vinylphosphonic Acid Derivatives Obtained by UV-Curing
Original language description
Vinylphosphonic acid is homopolymerized with dimethylvinylphosphonate by radical polymerization using using UV light and photoinitiator Darocur 4265 (3 wt%). The molar ratio between vinylphosphonic acid and dimethylvinylphosphonate is varied between 1:1 and 4:1, respectively. The obtained homopolymer of vinylphosphonic acid and copolymers are characterized by Fourier transform infrared spectroscopy (FTIR), thermal analysis and size exclusion chromatography - multi angle laser light scattering. The polymerization by UV light is efficient and an average molar mass of 34,200 g/mol is obtained for poly(vinylphosphonic acid) and in the range from 12,700 to 19,120 g/mol for copolymers, which also have a good thermal stability until 320 oC. The polymers structure allows the formation of random coil conformation. The copolymers are tested as inhibitors against corrosion of iron in NaCl aqueous solution, and, as a result, it was shown that these copolymers exhibit promising anticorrosion properties.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10404 - Polymer science
Result continuities
Project
<a href="/en/project/LO1211" target="_blank" >LO1211: Materials Research Centre at FCH BUT- Sustainability and Development</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
MACROMOLECULAR RESEARCH
ISSN
1598-5032
e-ISSN
2092-7673
Volume of the periodical
25
Issue of the periodical within the volume
3
Country of publishing house
KR - KOREA, REPUBLIC OF
Number of pages
8
Pages from-to
214-221
UT code for WoS article
000397986000003
EID of the result in the Scopus database
2-s2.0-85010977061