Thermodynamic Driving Forces and Chemical Reaction Fluxes; Reflections on the Steady State
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F20%3APU136314" target="_blank" >RIV/00216305:26310/20:PU136314 - isvavai.cz</a>
Result on the web
<a href="https://www.mdpi.com/1420-3049/25/3/699" target="_blank" >https://www.mdpi.com/1420-3049/25/3/699</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/molecules25030699" target="_blank" >10.3390/molecules25030699</a>
Alternative languages
Result language
angličtina
Original language name
Thermodynamic Driving Forces and Chemical Reaction Fluxes; Reflections on the Steady State
Original language description
Molar balances of continuous and batch reacting systems with a simple reaction are analyzed from the point of view of finding relationships between the thermodynamic driving force and the chemical reaction rate. Special attention is focused on the steady state, which has been the core subject of previous similar work. It is argued that such relationships should also contain, besides the thermodynamic driving force, a kinetic factor, and are of a specific form for a specific reacting system. More general analysis is provided by means of the non-equilibrium thermodynamics of linear fluid mixtures. Then, the driving force can be expressed either in the Gibbs energy (affinity) form or on the basis of chemical potentials. The relationships can be generally interpreted in terms of force, resistance and flux.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
MOLECULES
ISSN
1420-3049
e-ISSN
—
Volume of the periodical
25
Issue of the periodical within the volume
3
Country of publishing house
CH - SWITZERLAND
Number of pages
10
Pages from-to
1-10
UT code for WoS article
000515384800269
EID of the result in the Scopus database
2-s2.0-85079235530