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Negative effect of Zinc compounds on hydration kinetics of ordinary Portland cement

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F21%3APU137892" target="_blank" >RIV/00216305:26310/21:PU137892 - isvavai.cz</a>

  • Result on the web

    <a href="https://iopscience.iop.org/article/10.1088/1757-899X/1039/1/012004" target="_blank" >https://iopscience.iop.org/article/10.1088/1757-899X/1039/1/012004</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1088/1757-899X/1039/1/012004" target="_blank" >10.1088/1757-899X/1039/1/012004</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Negative effect of Zinc compounds on hydration kinetics of ordinary Portland cement

  • Original language description

    Heavy metals have significant effect on cement hydration mechanism and kinetics. The recycling of waste materials leads to increase of content of heavy metals in various industrial products and visibly affects properties of the Portland cement. One of the heavy metals that has been known to drastically increase the setting time is Zinc. Zinc forms various hydroxyl species with calcium cations. Pore solution thus has lowered concentration of calcium which suppresses formation of portlandite. Due to insufficient concentration of calcium the formation of CSH gel and further hydration of clinker grains is inhibited The aim of this study is to quantify the negative effects of Zinc at different concentrations at ambient temperature of 20 °C. Isoperibolic calorimetry was used to measure the negative effects of zinc on hydration kinetics of ordinary Portland cement. Zinc was added to the cement in the form of two soluble salts of Zn(NO3)2 hydrate, ZnCl2 and a poorly soluble compound ZnO. The concentration of zinc added was chosen between 0.1 and 1 mass % of clinker. Significant retardation of cement hydration with increasing zinc content was proven.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    International Conference Building Materials, Products and Technologies

  • ISBN

  • ISSN

    1757-8981

  • e-ISSN

  • Number of pages

    9

  • Pages from-to

    1-9

  • Publisher name

    IOP Publishing

  • Place of publication

    neuveden

  • Event location

    Telč

  • Event date

    Jun 2, 2020

  • Type of event by nationality

    EUR - Evropská akce

  • UT code for WoS article