Biobased Nonvolatile Rheology Modifier as a Superior Alternative to Styrene for Pultrusion
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F26%3A0198319" target="_blank" >RIV/00216305:26310/26:0198319 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acssuschemeng.5c03049" target="_blank" >https://pubs.acs.org/doi/10.1021/acssuschemeng.5c03049</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acssuschemeng.5c03049" target="_blank" >10.1021/acssuschemeng.5c03049</a>
Alternative languages
Result language
angličtina
Original language name
Biobased Nonvolatile Rheology Modifier as a Superior Alternative to Styrene for Pultrusion
Original language description
Sustainable and well-performing biobased compounds have attracted enormous attention for modern industrial applications. This work presents isosorbide monomethacrylate as a nonvolatile, reactive, liquid, and polar compound capable of substituting for styrene in conventional pultrusion. This proposed molecule was synthesized through an industrially scalable approach, ensuring a high product yield, negligible residue generation, and complete separation of secondary products. Isosorbide monomethacrylate exhibits lower curing reaction temperatures and volatility compared with currently used styrene. Its diluting potential was investigated and quantified using the Arrhenius temperature dependency. A successful pultrusion was performed using isosorbide monomethacrylate as a diluent, resulting in similar thermal stability and flexural modulus as the commercial composites. The isosorbide monomethacrylate-containing composites exhibited an almost 16% increase in the flexural strength and a more than 13% increase in the interlaminar shear strength. Therefore, this proposed, synthesized, and characterized molecule holds enormous potential to substitute for styrene for high-performance pultrusion applications.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Sustainable Chemistry & Engineering
ISSN
2168-0485
e-ISSN
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Volume of the periodical
14
Issue of the periodical within the volume
26
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
1-7
UT code for WoS article
001521219300001
EID of the result in the Scopus database
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