Functionalization of Open Two-Dimensional Metal?Organic Templates through the Selective Incorporation of Metal Atoms
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F13%3APU103573" target="_blank" >RIV/00216305:26620/13:PU103573 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Functionalization of Open Two-Dimensional Metal?Organic Templates through the Selective Incorporation of Metal Atoms
Original language description
Surface-confined molecular networks can serve as templates to steer the adsorption and organization of secondary ligands, metal atoms, and clusters. Here, the incorporation of Ni atoms and clusters into open two-dimensional robust metal?organic templatesself-assembled from butadiyne dibenzoic acid molecules and Fe atoms on Au(111) and Ag(100) surfaces is investigated by scanning tunneling microscopy. The metal substrate plays a crucial role in the interaction of Ni atoms with the metal?organic host networks. On Ag(100) the metal?organic template steers the growth of Ni clusters underneath the network pattern near the central butadiyne moiety. In contrast, on Au(111) Ni interacts preferentially with the benzene rings forming size-limited clusters inside the network cavities. Thereby, on both surfaces Ni clusters consisting of a few atoms with both high areal density and thermal stability up to 450 K are realized. The Ni-functionalized networks enable the coordination of additional mole
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
<a href="/en/project/ED1.1.00%2F02.0068" target="_blank" >ED1.1.00/02.0068: Central european institute of technology</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Physical Chemistry C (print)
ISSN
1932-7447
e-ISSN
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Volume of the periodical
117
Issue of the periodical within the volume
17
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
8871-8877
UT code for WoS article
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EID of the result in the Scopus database
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