Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F14%3APU112373" target="_blank" >RIV/00216305:26620/14:PU112373 - isvavai.cz</a>

Result on the web

<a href="http://ecst.ecsdl.org/content/63/1/145.abstract" target="_blank" >http://ecst.ecsdl.org/content/63/1/145.abstract</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1149/06301.0145ecst" target="_blank" >10.1149/06301.0145ecst</a>

Result language

angličtina

Original language name

Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode

Original language description

The tacit assumption in an electrochemical experiment is that a properly set up electrochemical cell, working electrode, counter electrode, reference electrode and a potentiostat, will perform an experiment by "applying potential on the working electrode" without any need to consider the properties of the reference electrodes, the effect of electrochemistry on the counter electrode and the real properties of the potentiostat. While this is in first approximation a valid assumption, in the extremes it is also necessary to consider the other parts of the system. In this work we visit two interesting cases that may lead to experimental artifacts. The first is the effect of electrochemical solution changes during impedance measurement. The second is effect of the time constant of a reference electrode on an impedance measurement in an electrochemical cell.

Czech name

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Czech description

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Type

D - Article in proceedings

CEP classification

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OECD FORD branch

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Project

<a href="/en/project/ED1.1.00%2F02.0068" target="_blank" >ED1.1.00/02.0068: Central european institute of technology</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2014

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection

15th International Conference on Advanced Batteries, Accumulators and Fuel Cells (ABAF 2014)

ISBN

978-1-62332-230-4

ISSN

1938-5862

e-ISSN

1938-6737

Number of pages

11

Pages from-to

145-155

Publisher name

The Electrochemical Society

Place of publication

Pennington, NJ

Event location

Brno

Event date

Aug 24, 2014

Type of event by nationality

WRD - Celosvětová akce

UT code for WoS article

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