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High-resolution characterization of hexagonal boron nitride coatings exposed to aqueous and air oxidative environments

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F17%3APU123935" target="_blank" >RIV/00216305:26620/17:PU123935 - isvavai.cz</a>

  • Result on the web

    <a href="https://link.springer.com/article/10.1007%2Fs12274-016-1393-2" target="_blank" >https://link.springer.com/article/10.1007%2Fs12274-016-1393-2</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s12274-016-1393-2" target="_blank" >10.1007/s12274-016-1393-2</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    High-resolution characterization of hexagonal boron nitride coatings exposed to aqueous and air oxidative environments

  • Original language description

    Hexagonal boron nitride (h-BN) is believed to offer better passivation to metallic surfaces than graphene owing to its insulating nature, which facilitates blocking the flow of electrons, thereby preventing the occurrence of galvanic reactions. Nevertheless, this may not be the case when an h-BN-protected material is exposed to aqueous environments. In this work, we analyzed the stability of mono and multilayer h-BN stacks exposed to H2O2 and atmospheric conditions. Our experiments revealed that monolayer h-BN is as inefficient as graphene as a protective coating when exposed to H2O2. Multilayer h-BN offered a good degree of protection. Monolayer h-BN was found to be ineffective in an air atmosphere as well. Even a 10–15 layers-thick h-BN stack could not completely protect the surface of the metal under consideration. By combining Auger electron spectroscopy and secondary ion mass spectrometry techniques, we observed that oxygen could diffuse through the grain boundaries of the h-BN stack to reach the metallic substrate. Fortunately, because of the diffusive nature of the process, the oxidized area did not increase with time once a saturated state was reached. This makes multilayer (not monolayer) h-BN a suitable long-term oxidation barrier. Oxygen infiltration could not be observed by X-ray photoelectron spectroscopy. This technique cannot assess the chemical composition of the deeper layers of a material. Hence, the previous reports, which relied on XPS to analyze the passivating properties of h-BN and graphene, may have ignored some important subsurface phenomena. The results obtained in this study provide new insights into the passivating properties of mono and multilayer h-BN in aqueous media and the degradation kinetics of h-BN-coated metals exposed to an air environment.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Nano Research

  • ISSN

    1998-0124

  • e-ISSN

    1998-0000

  • Volume of the periodical

    10

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    CN - CHINA

  • Number of pages

    10

  • Pages from-to

    2046-2055

  • UT code for WoS article

    000401320700019

  • EID of the result in the Scopus database

    2-s2.0-85010789957