Complex k-uniform tilings by a simple bitopic precursor self-assembled on Ag(001) surface
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F20%3APU136792" target="_blank" >RIV/00216305:26620/20:PU136792 - isvavai.cz</a>
Result on the web
<a href="https://www.nature.com/articles/s41467-020-15727-6" target="_blank" >https://www.nature.com/articles/s41467-020-15727-6</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1038/s41467-020-15727-6" target="_blank" >10.1038/s41467-020-15727-6</a>
Alternative languages
Result language
angličtina
Original language name
Complex k-uniform tilings by a simple bitopic precursor self-assembled on Ag(001) surface
Original language description
The realization of complex long-range ordered structures in a Euclidean plane presents a significant challenge en route to the utilization of their unique physical and chemical properties. Recent progress in on-surface supramolecular chemistry has enabled the engineering of regular and semi-regular tilings, expressing translation symmetric, quasicrystalline, and fractal geometries. However, the k-uniform tilings possessing several distinct vertices remain largely unexplored. Here, we show that these complex geometries can be prepared from a simple bitopic molecular precursor – 4,4’-biphenyl dicarboxylic acid (BDA) – by its controlled chemical transformation on the Ag(001) surface. The realization of 2- and 3-uniform tilings is enabled by partially carboxylated BDA mediating the seamless connection of two distinct binding motifs in a single long-range ordered molecular phase. These results define the basic self-assembly criteria, opening way to the utilization of complex supramolecular tilings.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
NATURE COMMUNICATIONS
ISSN
2041-1723
e-ISSN
—
Volume of the periodical
11
Issue of the periodical within the volume
1
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
1-6
UT code for WoS article
000558826300001
EID of the result in the Scopus database
2-s2.0-85083765981