Catalyst Formation and In Operando Monitoring of the Electrocatalytic Activity in Flow Reactors
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F21%3APU141637" target="_blank" >RIV/00216305:26620/21:PU141637 - isvavai.cz</a>
Alternative codes found
RIV/62156489:43210/21:43920254
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acsami.1c09127" target="_blank" >https://pubs.acs.org/doi/10.1021/acsami.1c09127</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsami.1c09127" target="_blank" >10.1021/acsami.1c09127</a>
Alternative languages
Result language
angličtina
Original language name
Catalyst Formation and In Operando Monitoring of the Electrocatalytic Activity in Flow Reactors
Original language description
Flow reactors are of increasing importance and have become crucial devices due to their wide application in chemical synthesis, electrochemical hydrogen evolution reaction (HER), or electrochemical waste water treatment. In many of these applications, catalyst materials such as transition-metal chalcogenides (TMCs) for the HER, provide the desired electrochemical reactivity for the HER. Generally, the flow electrolyzers' performance is evaluated as the overall output, but the decrease in activity of the electrolyzer is due to localized failure of the catalyst. Herein, we present a method for the spatially resolved (tens of micrometers) In Operando analysis of the catalytic activity under real operation conditions as well as the localized deposition of the catalyst in an operating model flow reactor. For these purposes, scanning electrochemical microscopy was applied for MoSx catalyst deposition and for localized tracking of the TMC activity with a resolution of 25 mu m. This approach offers detailed information about the catalytic performance and should find broad application for the characterization and optimization of flow reactor catalysis under real operational conditions.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
21001 - Nano-materials (production and properties)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS APPL MATER INTER
ISSN
1944-8244
e-ISSN
1944-8252
Volume of the periodical
13
Issue of the periodical within the volume
30
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
35777-35784
UT code for WoS article
000683741400049
EID of the result in the Scopus database
2-s2.0-85111575858