Spin crossover metal-organic frameworks with inserted photoactive guests: on the quest to control the spin state by photoisomerization
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F21%3APU142301" target="_blank" >RIV/00216305:26620/21:PU142301 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/21:73609440
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2021/DT/D1DT01057C" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2021/DT/D1DT01057C</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d1dt01057c" target="_blank" >10.1039/d1dt01057c</a>
Alternative languages
Result language
angličtina
Original language name
Spin crossover metal-organic frameworks with inserted photoactive guests: on the quest to control the spin state by photoisomerization
Original language description
Three Hofmann-like metal-organic frameworks {Fe(bpac)[Pt(CN)(4)]}center dot G (bpac = 1,2-bis(4-pyridyl)acetylene) were synthesized with photoisomerizable guest molecules (G = trans-azobenzene, trans-stilbene or cis-stilbene) and were characterized by elemental analysis, thermogravimetry and powder X-ray diffraction. The insertion of guest molecules and their conformation were inferred from Raman and FTIR spectra and from single-crystal X-ray diffraction and confronted with computational simulation. The magnetic and photomagnetic behaviors of the framework are significantly altered by the different guest molecules and different conformations. On the other hand, photoisomerization of the guest molecules becomes strongly hindered by the framework.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/LQ1601" target="_blank" >LQ1601: CEITEC 2020</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Dalton Transactions
ISSN
1477-9226
e-ISSN
1477-9234
Volume of the periodical
50
Issue of the periodical within the volume
25
Country of publishing house
GB - UNITED KINGDOM
Number of pages
12
Pages from-to
8877-8888
UT code for WoS article
000658796700001
EID of the result in the Scopus database
2-s2.0-85108881451