Trigonally Distorted Hexacoordinate Co(II) Single-Ion Magnets
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU144126" target="_blank" >RIV/00216305:26620/22:PU144126 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/22:73615115
Result on the web
<a href="https://www.mdpi.com/1996-1944/15/3/1064" target="_blank" >https://www.mdpi.com/1996-1944/15/3/1064</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/ma15031064" target="_blank" >10.3390/ma15031064</a>
Alternative languages
Result language
angličtina
Original language name
Trigonally Distorted Hexacoordinate Co(II) Single-Ion Magnets
Original language description
By simple reactions involving various cobalt(II) carboxylates (acetate and in situ prepared pivalate and 4-hydroxybenzoate salts) and neocuproine (neo), we were able to prepare three different carboxylate complexes with the general formula [Co(neo)(RCOO)(2)] (R = -CH3 for 1, (CH3)(3)C- for 2, and 4OH-C4H6- for 3). The [Co(neo)(RCOO)(2)] molecules in the crystal structures of 1-3 adopt a rather distorted coordination environment, with the largest trigonal distortion observed for 1, whereas 2 and 3 are similarly distorted from ideal octahedral geometry. The combined theoretical and experimental investigations of magnetic properties revealed that the spin Hamiltonian formalism was not a valid approach and the L-S Hamiltonian had to be used to reveal very large magnetic anisotropies for 1-3. The measurements of AC susceptibility showed that all three compounds exhibited slow-relaxation of magnetization in a weak external static magnetic field, and thus can be classified as field-induced single-ion magnets. It is noteworthy that 1 also exhibits a weak AC signal in a zero-external magnetic field.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/LTAUSA19060" target="_blank" >LTAUSA19060: Spectroscopy of Single-Molecule Magnets Using Graphene-Based Bolometers</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Materials
ISSN
1996-1944
e-ISSN
—
Volume of the periodical
15
Issue of the periodical within the volume
3
Country of publishing house
CH - SWITZERLAND
Number of pages
15
Pages from-to
1064-1064
UT code for WoS article
000754839600001
EID of the result in the Scopus database
2-s2.0-85123615047