Electrically reading a light-driven molecular switch on 2D-Ti3C2Tx MXene via molecular engineering: towards responsive MXetronics

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU145577" target="_blank" >RIV/00216305:26620/22:PU145577 - isvavai.cz</a>
Alternative codes found
RIV/61989100:27240/22:10250317
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2022/TA/D2TA03349F" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2022/TA/D2TA03349F</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d2ta03349f" target="_blank" >10.1039/d2ta03349f</a>

Result language
angličtina
Original language name
Electrically reading a light-driven molecular switch on 2D-Ti3C2Tx MXene via molecular engineering: towards responsive MXetronics
Original language description
The contemporary digital revolution, which demands for miniaturized electronics, has prompted the search for molecule-based nanomaterials that handle some of the computational logic functions-which relates the concept of zeros (0) and ones (1) in binary code-reached by mainstream silicon-based semiconductor technology. Herein, the feasibility of emerging 2D transition metal carbide (MXene) derivatives to write, erase and readout bistable molecular switches has been elucidated. As a first demonstration of applicability, 2D-Ti3C2Tx MXene has been covalently functionalized with an optically active molecule as azobenzene (AZO), in which the photo-driven inputs of the AZO isomerization (E-AZO@Ti3C2Tx <-> Z-AZO@Ti3C2Tx) resulted in two distinguished electrical states when it was immobilized in an emerging 3D-printed transducer. Thus, this work provides the basis towards the yet undisclosed concept of "Responsive MXetronics" by molecularly engineering smart MXenes to perform logic (opto)electronic tasks.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20505 - Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics; filled composites)

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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