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2D Functionalized Germananes: Synthesis and Applications

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F23%3APU147337" target="_blank" >RIV/00216305:26620/23:PU147337 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989100:27240/23:10252982

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/10.1002/adma.202207196" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/adma.202207196</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/adma.202207196" target="_blank" >10.1002/adma.202207196</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    2D Functionalized Germananes: Synthesis and Applications

  • Original language description

    In the realm of 2D layered materials, the monoelemental group 14 Xene, germanene, as the germanium analog of graphene, has emerged as the next prospective candidate. Preceded by silicon, germanium is widely used in the semiconductor industry; thus, germanene is deemed compatible with existing semiconductor technologies. Germanene consists of mixed sp(2)-sp(3)-hybridized networks in a buckled hexagonal honeycomb structure. Chemical exfoliation of Zintl phases, such as CaGe2, specifically the topotactical deintercalation in acidic media, removes the alkaline earth metal ions Ca2+, giving rise to layered germanane (germanene with the Ge centers covalently saturated with terminal hydrogen atoms). Diverse variants of functionalized germananes (with covalent group(s) termination) can be obtained by varying the topotactical deintercalation precursors, elevating the game with limitless functionalization possibilities for customizable properties or new functionalities. The preparation of Zintl phases to the details of functionalized and modified germananes and their properties, and the additional exfoliation step to achieve mono- or few-layer germananes, are comprehensively covered. The progress and challenges of 2D functionalized germananes in optoelectronics, catalysis, energy conversion and storage, sensors, and biomedical areas are reviewed. This review provides insight into designing and exploring this class of atomically thin semiconductors in realizing future nanoarchitectonics.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Result continuities

  • Project

    <a href="/en/project/GX19-26896X" target="_blank" >GX19-26896X: 2D Nanomaterials Electrochemistry</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ADVANCED MATERIALS

  • ISSN

    0935-9648

  • e-ISSN

    1521-4095

  • Volume of the periodical

    35

  • Issue of the periodical within the volume

    7

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    37

  • Pages from-to

    „2207196“-„“

  • UT code for WoS article

    000905285400001

  • EID of the result in the Scopus database

    2-s2.0-85145314413