Variation of Spin-Transition Temperature in the Iron(III) Complex Induced by Different Compositions of the Crystallization Solvent
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F23%3APU148623" target="_blank" >RIV/00216305:26620/23:PU148623 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/23:73621967
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acs.cgd.2c01411" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.cgd.2c01411</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.cgd.2c01411" target="_blank" >10.1021/acs.cgd.2c01411</a>
Alternative languages
Result language
angličtina
Original language name
Variation of Spin-Transition Temperature in the Iron(III) Complex Induced by Different Compositions of the Crystallization Solvent
Original language description
We crystallized the Schiff-base iron(III) spin-crossover complex [Fe(3,5Cl-L5)(NCSe)] from different two-component solvent mixtures containing methanol and chloroform (phi = V(CH3OH)/V(solvent) = 0.05, 0.25, 0.50, 0.83, and 1.00). The obtained crystalline products were characterized by X-ray diffraction, and it was confirmed that they are all composed of the same crystalline phase, and they do not contain any crystal solvent. However, significant differences in magnetic properties were observed, and thermal hysteresis changed from (in K) 121T down arrow and 134T up arrow for phi = 0.05 and 0.25, down to 72T down arrow and 96T up arrow for phi = 1.00. The crystal structures of the low-spin and high-spin phases were studied theoretically and experimentally.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
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Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Crystal Growth and Design
ISSN
1528-7483
e-ISSN
1528-7505
Volume of the periodical
23
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
1323-1329
UT code for WoS article
000934881600001
EID of the result in the Scopus database
2-s2.0-85148663549