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Laser-Induced MXene-Functionalized Graphene Nanoarchitectonics-Based Microsupercapacitor for Health Monitoring Application

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F23%3APU150076" target="_blank" >RIV/00216305:26620/23:PU150076 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989592:15640/23:73621606 RIV/61989100:27240/23:10253111 RIV/61989100:27740/23:10253111

  • Result on the web

    <a href="https://pubs.acs.org/doi/10.1021/acsnano.3c07319" target="_blank" >https://pubs.acs.org/doi/10.1021/acsnano.3c07319</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acsnano.3c07319" target="_blank" >10.1021/acsnano.3c07319</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Laser-Induced MXene-Functionalized Graphene Nanoarchitectonics-Based Microsupercapacitor for Health Monitoring Application

  • Original language description

    Microsupercapacitors (micro-SCs) with mechanical flexibility have the potential to complement or even replace microbatteries in the portable electronics sector, particularly for portable biomonitoring devices. The real-time biomonitoring of the human body's physical status using lightweight, flexible, and wearable micro-SCs is important to consider, but the main limitation is, however, the low energy density of micro-SCs as compared to microbatteries. Here using a temporally and spatially controlled picosecond pulsed laser, we developed high-energy-density micro-SCs integrated with a force sensing device to monitor a human body's radial artery pulses. The photochemically synthesized spherical laser-induced MXene (Ti3C2T x )-derived oxide nanoparticles uniformly attached to laser-induced graphene (LIG) act as active electrode materials for micro-SCs. The molecular dynamics simulations and detailed spectroscopic analysis reveal the synergistic interfacial interaction mechanism of Ti-O-C covalent bonding between MXene and LIG. The incorporation of MXene nanosheets improves the graphene sheet alignment and ion transport while minimizing self-restacking. Furthermore, the micro-SCs based on a nano-MXene-LIG hybrid demonstrate high mechanical flexibility, durability, ultrahigh energy density (21.16 x 10(-3) mWh cm(-2)), and excellent capacitance (similar to 100 mF cm(-2) @ 10 mV s(-1)) with long cycle life (91% retention after 10 000 cycles). Such a single-step roll-to-roll highly reproducible manufacturing technique using a picosecond pulsed laser to induce MXene-derived spherical oxide nanoparticles (size of quantum dots) attached uniformly to laser-induced graphene for biomedical device fabrication is expected to find a wide range of applications.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ACS Nano (e-ISSN)

  • ISSN

    1936-0851

  • e-ISSN

    1936-086X

  • Volume of the periodical

    17

  • Issue of the periodical within the volume

    20

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    14

  • Pages from-to

    20537-20550

  • UT code for WoS article

    001078935400001

  • EID of the result in the Scopus database

    2-s2.0-85175271339