Single Atom Catalyst for Nitrate-to-Ammonia Electrochemistry

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F26%3A0197277" target="_blank" >RIV/00216305:26620/26:0197277 - isvavai.cz</a>

Alternative codes found

RIV/61989100:27240/25:10255641

Result on the web

<a href="https://onlinelibrary.wiley.com/doi/10.1002/smll.202403515" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/smll.202403515</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/smll.202403515" target="_blank" >10.1002/smll.202403515</a>

Result language

angličtina

Original language name

Single Atom Catalyst for Nitrate-to-Ammonia Electrochemistry

Original language description

Various life forms suffer from the negative effects of nitrate when it accumulates in water bodies, which is a major concern in the present day. The removal of nitrate from water bodies is a critical challenge, and the most effective method to achieve that is to change it into ammonia. Ammonia is a clean energy source and a vital input for the fertilizer industry. The Haber-Bosch process, which dominates the industrial production of ammonia, requires a lot of energy. A more sustainable way to produce ammonia is to use nitrate-contaminated water and reduce it to ammonia through electrocatalysis. This review is constituted of amalgamated articles featuring unique conditions that affect the productivity and activity of the transition metal single atom catalyst (TNMSAC) for the electrocatalytic nitrate reduction to ammonia (NRA) reaction. It explores factors such as nitrate ion adsorption, the characteristics of the central electroactive transition metal, the type of coordinating atoms, the impact of potential on stability, and the interplay among single atoms on the selectivity and yield of ammonia gas. In addition, this review also covers advanced concepts such as dual-atom catalysts, dual single atom catalysts, and single atom alloys. The review will provide valuable guidance for enhanced comprehension and strategic designing of TNMSAC for the electrocatalytic conversion of NRA, which will contribute to achieving a green ammonia economy. This review constitutes articles which feature unique conditions that affect the productivity and activity of the transition metal single atom catalyst for the electrocatalytic nitrate to ammonia reaction. Factors such as nitrate ion adsorption, characteristics of the central electroactive transition metal, type of coordinating atoms, impact of potential on stability, and the interplay among single atoms on the selectivity and yield of ammonia have been explored. image

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

21001 - Nano-materials (production and properties)

Project

<a href="/en/project/LM2023051" target="_blank" >LM2023051: Research infrastructure CzechNanoLab</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2025

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Small

ISSN

1613-6810

e-ISSN

1613-6829

Volume of the periodical

21

Issue of the periodical within the volume

28

Country of publishing house

DE - GERMANY

Number of pages

21

Pages from-to

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UT code for WoS article

001322260600001

EID of the result in the Scopus database

2-s2.0-85205242851