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Rheological and calorimetric characterization of the role of CaCl2 on Portland cement early hydration

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F26232511%3A_____%2F16%3AN0000048" target="_blank" >RIV/26232511:_____/16:N0000048 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.researchgate.net/publication/306074385_Rheological_and_Calorimetric_Characterization_of_the_Role_of_CaCl2_on_Portland_Cement_Early_Hydration" target="_blank" >https://www.researchgate.net/publication/306074385_Rheological_and_Calorimetric_Characterization_of_the_Role_of_CaCl2_on_Portland_Cement_Early_Hydration</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.4028/www.scientific.net/MSF.865.17" target="_blank" >10.4028/www.scientific.net/MSF.865.17</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Rheological and calorimetric characterization of the role of CaCl2 on Portland cement early hydration

  • Original language description

    Paper describes a new way how to characterize early hydration and setting of Portland cement pastes with various dosages of setting accelerator CaCl2. The aim was not to characterize the role of well-known setting accelerator CaCl2 but to correlate rheology and calorimetry in view of early hydration of Portland cement. Characterization was based on measurements on rotational rheometer, isothermal calorimeter and semiadiabatic calorimeter. The courses of calorimetric exotherms in time were correlated to the development of the phase angle obtained by rheological oscillation tests. Heat flow peaks can be successfully correlated to rheological processes described by change of storage and elastic moduli up to the time that corresponds to the start of the setting which was found to be the limit for rheological tests. The start of the setting on calorimetric curve belongs to the onset point of the main silicate peak during acceleration period of hydration. The value of phase angle decreases as the setting cement paste changes from liquid to solid-like. Times of low values of phase angle ~ 2.5 (°) can be related to times of onset points of main peak for every dosage of setting accelerator.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    JN - Civil engineering

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Materials Science Forum

  • ISSN

    1662-9752

  • e-ISSN

  • Volume of the periodical

    2016

  • Issue of the periodical within the volume

    865

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    5

  • Pages from-to

    17 – 21

  • UT code for WoS article

  • EID of the result in the Scopus database