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Remobilization of HFSE, Y, and REE during Diagenetic Alteration of Heavy Minerals in Sandstones from the Chvalčov Site, Flysch Belt of the Outer Western Carpathians, Czech Republic

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F26232511%3A_____%2F24%3AN0000005" target="_blank" >RIV/26232511:_____/24:N0000005 - isvavai.cz</a>

  • Alternative codes found

    RIV/00023272:_____/23:10136169

  • Result on the web

    <a href="https://www.mdpi.com/2075-163X/14/1/1" target="_blank" >https://www.mdpi.com/2075-163X/14/1/1</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3390/min14010001" target="_blank" >10.3390/min14010001</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Remobilization of HFSE, Y, and REE during Diagenetic Alteration of Heavy Minerals in Sandstones from the Chvalčov Site, Flysch Belt of the Outer Western Carpathians, Czech Republic

  • Original language description

    An in situ electron microprobe study of detrital minerals yielded important insights into the diagenetic history of the Cretaceous-to-Paleogene flysch sandstones from the Chvalčov site, Rača Unit, Flysch Belt of the Outer Western Carpathians. Detrital titanite and a Fe-Ti mineral (probably ilmenite) were almost completely altered to TiO2 minerals, which also newly crystallized in intergranular spaces of sandstone. Brookite, anatase, and, exceptionally, rutile were identified by Raman spectroscopy. Authigenic TiO2 phases show complex composition with occasionally elevated contents of Fe, Nb, Zr, V, Sc, Cr, Al, Y, and/or P, which were likely sourced from altered neighboring heavy minerals. In addition, rare authigenic LREE- and Y-enriched apatite rims were observed on detrital apatite. The remobilization of REE, Y, and HFSE was likely mediated by acidic early diagenetic fluids enriched in fluoride and sulfate anions. The superimposed formation of calcite cement was associated with the dissolution of detrital garnet, feldspars, and quartz. The compositions of detrital apatite and garnet (Alm60-82Prp4-30Sps0-24Grs0-19) are comparable with those from adjacent parts of the Flysch Belt. Detrital rutile is enriched in Nb, V, Cr, and Zr. Our study illustrates the intensity of diagenetic alteration of detrital minerals in flysch sandstones as well as the usefulness of in-situ electron-microprobe investigations for the recognition of processes influencing heavy minerals in diagenetically altered sediments.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>SC</sub> - Article in a specialist periodical, which is included in the SCOPUS database

  • CEP classification

  • OECD FORD branch

    10505 - Geology

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Minerals

  • ISSN

    2075163X

  • e-ISSN

  • Volume of the periodical

    14

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    20

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database

    2-s2.0-85183409977