Detritiation of the Organic Material in the MSO Process

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F26722445%3A_____%2F24%3AN0000010" target="_blank" >RIV/26722445:_____/24:N0000010 - isvavai.cz</a>

Result on the web

<a href="https://www.tandfonline.com/doi/full/10.1080/15361055.2024.2305996" target="_blank" >https://www.tandfonline.com/doi/full/10.1080/15361055.2024.2305996</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/15361055.2024.2305996" target="_blank" >10.1080/15361055.2024.2305996</a>

Result language

angličtina

Original language name

Detritiation of the Organic Material in the MSO Process

Original language description

Tritium is a radioactive isotope of hydrogen, and due to its limited supply and related high price, it is necessary to recover it from tritiated materials via detritiation technologies. The number of tritiated materials arises during fusion. Tritium from fusion reactors is deposited in the outer layer of plasma-facing materials, which must be dealt with during maintenance or decommissioning processes. A second source of waste is laboratory equipment that could be contaminated with tritium.High-temperature treatment in an oxidation environment can achieve the release of tritium from metals or organic materials. The tritiated vapor is then captured in a series of water bubblers and reprocessed into pure T2. One of the high-temperature methods is molten salt oxidation (MSO), which uses high temperatures, alkaline salt, and an oxidative environment for flameless oxidation of different types of waste.This work aimed to simulate the detritiation processes of tritiated organic materials in MSO technology. First, a series of experiments with D2O absorbed in ion resins was conducted. The organic waste was decomposed within the molten salt, and the flue gas was measured to determine the oxidation efficiency. The D2O was captured in a series of water bubblers, and the water was then analyzed with attenuated total reflectance (ATR)-Fourier transform infrared spectroscopy (FTIR). The results showed that all deuterium in the form of D2O was caught in the first water bubbler. The capture efficiency ranged from 22.32% to 61.13%. The lower efficiency capture can be explained as D2O in water can form a HDO molecule and its correct determination is problematic.The second type of experiment was carried out with T2O with an activity of 851 Bq and with tritiated oil with an activity of 2495 Bq. The T2O was added to the set amount of ion resins and dosed into MSO. A peristaltic pump dosed the tritiated oil. The flue gas was measured to determine oxidation efficiency, and the T2O was captured within the water bubblers. The water was analyzed with liquid scintillation spectroscopy. The capture efficiency ranged between 76.42% to 97.87%. The results showed that this technology is suitable for the detritiation of tritiated organic materials.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

20305 - Nuclear related engineering; (nuclear physics to be 1.3);

Project

<a href="/en/project/9D22001" target="_blank" >9D22001: Implementation of activities described in the Roadmap to Fusion during Horizon Europe through a joint programme of the members of the EUROfusion consortium</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2024

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Fusion Science and Technology

ISSN

1536-1055

e-ISSN

1943-7641

Volume of the periodical

80

Issue of the periodical within the volume

1-4

Country of publishing house

US - UNITED STATES

Number of pages

9

Pages from-to

321-329

UT code for WoS article

001175531700001

EID of the result in the Scopus database

2-s2.0-85186236986