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Prediction of Vaporization Enthalpy for Pure Organic Compounds by a Group Contribution Method

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13440%2F03%3A00004215" target="_blank" >RIV/44555601:13440/03:00004215 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Prediction of Vaporization Enthalpy for Pure Organic Compounds by a Group Contribution Method

  • Original language description

    Enthalpy of vaporization have been estimated by a new group contribution methods. In this presentation the new group contribution method is presented. Estimation is performed at three levels. As a result this method is able to distinguish between some isomers, which is its unique feature in comparison with other common group contribution methods. Vaporization enthalpy prediction at 250C was performed by this approach with an absolute and a relative average errors of 1.01 kJ/mol and 2.3 %, resp. (for 792compounds) whereas the errors for estimation at the normal boiling temperature were as follows: 0.96 kJ/mol and 2.6 % (for 601 compounds).

  • Czech name

    Odhad výparné enthalpie čistých organických látek pomocí strukturně příspěvkové metody

  • Czech description

    Výparné entalpie čistých organických látek byly odhadnuty pomocí strukturně příspěvkové metody.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2003

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemické listy

  • ISSN

    0009-2770

  • e-ISSN

  • Volume of the periodical

    97

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    1

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database