Potential of mean force between ions in infinitely diluted simple short-range models of aqueous electrolytes

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13440%2F05%3A00004832" target="_blank" >RIV/44555601:13440/05:00004832 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Potential of mean force between ions in infinitely diluted simple short-range models of aqueous electrolytes

Original language description

As an attempt to assess the effect of the long-range electrostatic interactions in solutions of electrolytes, a simple short-range model (SSM) of electrolytes made up of primitive water and primitive ions (i.e., ions whose Coulombic interaction with water has been replaced by a triangular-well interaction) has been considered to compute the potential of mean force. The sizes of the primitive ions have been set so as to approximate realistic NaCl, Lil, and CsCl electrolytes. It is shown that despite themissing long-range Coulombic interaction the model captures the basic features of real electrolytes while the indirect, i.e. water mediated, potential of mean force in the SSM is in qualitative agreement with that of realistic models.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BL - Plasma physics and discharge through gases

OECD FORD branch

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Project

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Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2005

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Condensed Matter Physics

ISSN

1607-324X

e-ISSN

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Volume of the periodical

8

Issue of the periodical within the volume

2

Country of publishing house

UA - UKRAINE

Number of pages

10

Pages from-to

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UT code for WoS article

000231713000005

EID of the result in the Scopus database

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