Efect of the range of interactions on the propeties of fluids. Part II. Structure and phase behavior of acetonitrile, hydrogen fluoride, and formic acis.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13440%2F05%3A00005500" target="_blank" >RIV/44555601:13440/05:00005500 - isvavai.cz</a>

Alternative codes found

RIV/67985858:_____/05:00359688

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Efect of the range of interactions on the propeties of fluids. Part II. Structure and phase behavior of acetonitrile, hydrogen fluoride, and formic acis.

Original language description

To complete the study on the effect of the long-range part of Coulombic interactions on properties of complex polar and associating fluids, we have investigated in detail three compounds with extreme features: acetonitrile for its unusually large dipolemoment, hydrogen fluoride with very strong hydrogen bonding, and formic acid for its potential formation of different n-mers in liquid and gaseous phases. The effect of the long-range Coulombic interactions on both the structure and thermodynamics of thehomogeneous phase, and on the vapor-liquid equilibria has been examined using the same decomposition of realistic potential models into a short-range part and a residual pan as in the previous paper [Kettler, M.; et al. J. Phys. Chem. B 2002, 106, 7537-7546]. The present results fully confirm the previous findings that the properties of polar and associating systems are determined primarily by the short-range interactions regardless of their nature, i.e., contributions arising from the

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BE - Theoretical physics

OECD FORD branch

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Project

<a href="/en/project/IAA4072303" target="_blank" >IAA4072303: General eyuations of state of fluids from molecular principles and their application to thermophysical properties of fluid mixtures</a><br>

Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2005

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of physical chemistry. B, Condensed matter, materials, surfaces, interfaces & biophysical

ISSN

1520-6106

e-ISSN

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Volume of the periodical

109

Issue of the periodical within the volume

19

Country of publishing house

US - UNITED STATES

Number of pages

15

Pages from-to

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UT code for WoS article

000229134000078

EID of the result in the Scopus database

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