Excluded volume versus hydrogen bonding: complementary or incompatible concepts?
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13440%2F12%3A43884680" target="_blank" >RIV/44555601:13440/12:43884680 - isvavai.cz</a>
Alternative codes found
RIV/67985858:_____/12:00424670
Result on the web
<a href="http://www.tandfonline.com/doi/pdf/10.1080/00268976.2012.689875" target="_blank" >http://www.tandfonline.com/doi/pdf/10.1080/00268976.2012.689875</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/00268976.2012.689875" target="_blank" >10.1080/00268976.2012.689875</a>
Alternative languages
Result language
angličtina
Original language name
Excluded volume versus hydrogen bonding: complementary or incompatible concepts?
Original language description
An attempt has been made to assess individual effects of the repulsive and attractive interactions on the structure of associating fluids using short-range models descending from parent realistic models. It is shown that neither the excluded volume (repulsive interactions) nor the hydrogen bonding (attractive interactions) considered separately are able to produce the correct structure. However, when both these types of interactions are considered together, they faithfully reproduce the structure of water and other associating fluids. Consequently, although some properties of aqueous systems can be explained qualitatively/intuitively by hydrogen bonding only, disregarding simultaneously the excluded volume effects may be misleading.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/IAA400720802" target="_blank" >IAA400720802: Simple and complex models of aqueous solutions: The effect of nonadditive interactions</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Molecular Physics
ISSN
0026-8976
e-ISSN
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Volume of the periodical
110
Issue of the periodical within the volume
24
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
2987-2992
UT code for WoS article
000311782000001
EID of the result in the Scopus database
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