Toward a simple molecular theory of hydrophobic hydration
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13440%2F14%3A43885124" target="_blank" >RIV/44555601:13440/14:43885124 - isvavai.cz</a>
Alternative codes found
RIV/67985858:_____/14:00485688
Result on the web
<a href="http://dx.doi.org/10.1016/j.molliq.2013.06.020" target="_blank" >http://dx.doi.org/10.1016/j.molliq.2013.06.020</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molliq.2013.06.020" target="_blank" >10.1016/j.molliq.2013.06.020</a>
Alternative languages
Result language
angličtina
Original language name
Toward a simple molecular theory of hydrophobic hydration
Original language description
A perturbation theory of water is extended to mixtures, and its application to aqueous solutions of noble gases is presented. The present approach is based on the thermodynamic perturbation theory of the primitive models of associating fluids, substituting the reference pseudo-hard-body term by a hard-sphere/pseudo-hard-body mixture term and introducing appropriate corrections. The primitive models are constructed in a rigorous way from realistic parents. The procedure yields equations of state allowingfor the determination of all residual properties. The residual chemical potential is expressed and subsequently the Henry's law constants of noble gases, from He to Xe, are evaluated as functions of temperature showing qualitative agreement with experimental data. Throughout the procedure, no experimental data are used to adjust the parameters or to fine-tune the results.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Molecular Liquids
ISSN
0167-7322
e-ISSN
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Volume of the periodical
189
Issue of the periodical within the volume
SI
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
7
Pages from-to
13-19
UT code for WoS article
000330912400003
EID of the result in the Scopus database
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