Tuning the photophysical properties of Anti-B18H22[1]

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13440%2F15%3A43886872" target="_blank" >RIV/44555601:13440/15:43886872 - isvavai.cz</a>

Alternative codes found

RIV/61388980:_____/15:00443207

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Tuning the photophysical properties of Anti-B18H22[1]

Original language description

The tuning of the photophysical properties of the highly fluorescent boron hydride cluster anti-B18H22 (1), by straight-forward chemical substitution to produce 4,4'-(HS)(2)-anti-B18H20 (2), facilitates intersystem crossing from excited singlet states toa triplet manifold.[1] This subsequently enhances O-2((1)Delta(g)) singlet oxygen production from a quantum yield of Phi(Delta) similar to 0.008 in 1 to 0.59 in 2. This contribution describes the synthesis and full structural characterization of the newcompound 4,4'-(HS) 2-anti-B18H20 (2) and uses UV-vis spectroscopy coupled with DFT and ab initio computational studies to delineate and explain its photophysical properties. Additionally, we will report on new fluorescent derivatives of anti-B18H22 andtheir immobilisation on solid nanostructured substrates.

Czech name

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Czech description

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Type

D - Article in proceedings

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection

6th NANOCON International Conference

ISBN

978-80-87294-53-6

ISSN

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e-ISSN

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Number of pages

4

Pages from-to

300-303

Publisher name

TANGER LTD

Place of publication

Ostrava

Event location

Brno, CZECH REPUBLIC

Event date

Nov 5, 2014

Type of event by nationality

WRD - Celosvětová akce

UT code for WoS article

000350636300050