Synthesis and fluorophilicity of compounds with tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silyl substituent

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13440%2F15%3A43887542" target="_blank" >RIV/44555601:13440/15:43887542 - isvavai.cz</a>
Alternative codes found
RIV/67985858:_____/15:00456711
Result on the web
<a href="http://dx.doi.org/10.1016/j.jfluchem.2015.06.017" target="_blank" >http://dx.doi.org/10.1016/j.jfluchem.2015.06.017</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jfluchem.2015.06.017" target="_blank" >10.1016/j.jfluchem.2015.06.017</a>

Result language
angličtina
Original language name
Synthesis and fluorophilicity of compounds with tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silyl substituent
Original language description
substituent was synthesized starting from 3-halopropyltris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)- silanes. The series can be divided into three subgroups based on the potential use of theses compounds: (i) cyclopentadienyl transition metal complexes and N-ligands, (ii) synthons for azide-alkyne [3+2] cycloaddition, (iii) imidazolium-type ionic liquids. Partition coefficients between fluorous and organic phases in a standard system perfluoro(methylcyclohexane)/toluene were measured using variousmethods. Both new and several similar previously prepared compounds were included. Gravimetry and 19F NMR spectroscopy were used for all the compounds whereas gas chromatography and AAS/AES spectroscopy were used where appropriate. Generally, consistentvalues were obtained by different methods. The partition coefficients of the compounds ranged from 10 to 100 with the exception of cyclopentadienyl complexes, where the partition coefficients were an order of magnitude lower, and ionic li
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP106%2F12%2F1372" target="_blank" >GAP106/12/1372: Highly fluorous cyclopentadienes for applications in catalysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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