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Taking the power of plasmon-assisted chemistry on copper NPs: Preparation and application of COFs nanostructures for CO2 sensing in water

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13440%2F20%3A43895702" target="_blank" >RIV/44555601:13440/20:43895702 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22310/20:43921238 RIV/60461373:22320/20:43921238 RIV/00216208:11320/20:10422436

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S1387181120305771?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1387181120305771?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.micromeso.2020.110577" target="_blank" >10.1016/j.micromeso.2020.110577</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Taking the power of plasmon-assisted chemistry on copper NPs: Preparation and application of COFs nanostructures for CO2 sensing in water

  • Original language description

    In this contribution, we report a novel, mild, and energy efficient approach for the preparation of covalent organic frameworks (COFs) at ambient conditions. For the first time, powerful plasmonic chemistry was applied for the synthesis of carbon triazine framework (CTF-1) on copper nanoparticles (CuNPs) as an alternative to common synthetic procedures, which are restricted by harsh experimental conditions and low throughput. Plasmonic CuNPs were functionalized by 4-cyanophenyl groups, which were further used as anchoring groups for surface-assisted growth of CTF-1 under the illumination at wavelength corresponding to plasmon absorption band of CuNPs. Prepared CuNPs@CTF-1 structure exhibit core-shell nature and outstanding sensing properties for CO2 in water. In the next step, the copper core was dissolved, and resulting CTF-1 powder with high surface area was isolated. Generally, our pioneering work demonstrates the power of plasmonic chemistry for unpretentious COF synthesis performed in mild and cheap manner without any special apparatus and harsh conditions, as well as for the preparation of applied sensing material.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20501 - Materials engineering

Result continuities

  • Project

    <a href="/en/project/GA20-01639S" target="_blank" >GA20-01639S: New Generation of Organic/Inorganic Materials for Carbon Dioxide Detection, Capture and Utilization</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Microporous and Mesoporous Materials

  • ISSN

    1387-1811

  • e-ISSN

  • Volume of the periodical

    2020

  • Issue of the periodical within the volume

    309

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    8

  • Pages from-to

    1-8

  • UT code for WoS article

    000577315700001

  • EID of the result in the Scopus database

    2-s2.0-85089903606