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Gibbs Energies of Transfer of Alkali Metal Cations between Mutually Saturated Water-Solvent Systems Determined from Extraction Experiments with Radiotracer 137 Cs

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46356088%3A_____%2F06%3A%230000405" target="_blank" >RIV/46356088:_____/06:#0000405 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Gibbs Energies of Transfer of Alkali Metal Cations between Mutually Saturated Water-Solvent Systems Determined from Extraction Experiments with Radiotracer 137 Cs

  • Original language description

    Thermodynamic standard Gibbs energies of transfer of alkali metal cations related to Cs+ cation between several mutually saturated solvents of the type water-solvent were calculated from determined extraction exchange constants. The used liquid-liquid extraction method with radioactive tracing by 137Cs permits attaining higher precision of the values as compared to the methods used up to now. The data for o-nitrophenyloctyl ether, 1,2-dichloroethane, 1-octanol, dioctyladipate and dioctylsebacate are reported.

  • Czech name

    Gibbsovy energie přenosu kationtů alkalických kovů mezi vzájemně nasycenými rozpouštědly stanovené pomocí 137 stopovače

  • Czech description

    Termodynamické standardní Gibbsovy energie přenosu kationtů alkalických kovů vztažené na Cs+ mezi několika vzájemně nasycenými rozpouštědly byly vypočteny ze stanovených extrakčně-výměnných konstant. Použitá extrakční metoda s využitím značkovače 137 Csumožňuje dosažení vyšší přesnosti ve srovnání s doposud použitými metodami. Byla získána data pro o-nitrofenyloktyl ether, 1,2- dichloroetan, 1-oktanol, dioktyladipát a dioctylsebakát.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA104%2F05%2F2667" target="_blank" >GA104/05/2667: Extraction methods for the isolation of fission products from radioactive waste by using new ecological solvents and fulfilling the needs of 21. centaury techno</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2006

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    J. Phys. Chem. B

  • ISSN

    1520-6106

  • e-ISSN

  • Volume of the periodical

    110

  • Issue of the periodical within the volume

    16

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    8432-8440

  • UT code for WoS article

  • EID of the result in the Scopus database