Very Selective Synergistic Extraction of Univalent Cations into Nitrobenzene and Phenyltrifluoromethyl Sulfone Solutions of Dicarbollylcobaltate in the Presence of Some Calix[4]arene-crowns-6
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46356088%3A_____%2F20%3AN0000035" target="_blank" >RIV/46356088:_____/20:N0000035 - isvavai.cz</a>
Alternative codes found
RIV/60460709:41330/20:85124 RIV/60461373:22340/20:43920609
Result on the web
<a href="https://link.springer.com/article/10.1007%2Fs10953-020-01033-8" target="_blank" >https://link.springer.com/article/10.1007%2Fs10953-020-01033-8</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10953-020-01033-8" target="_blank" >10.1007/s10953-020-01033-8</a>
Alternative languages
Result language
angličtina
Original language name
Very Selective Synergistic Extraction of Univalent Cations into Nitrobenzene and Phenyltrifluoromethyl Sulfone Solutions of Dicarbollylcobaltate in the Presence of Some Calix[4]arene-crowns-6
Original language description
The exchange extraction constants corresponding to the general equilibria M+(aq) + NaL+(org) reversible arrow ML+(org) + Na+(aq) and the respective M+(aq) + CsL+(org) reversible arrow ML+(org) + Cs+(aq), taking place in the two-phase water-nitrobenzene and water-phenyltrifluoromethyl sulfone (abbrev. FS 13) systems (M+ = Li+, H3O+, Ag+, K+, NH4+, Tl+, Rb+; L = calix[4]arene-bis(t-octylbenzo-18-crown-6), 1,3-alternate-25,27-bis(1-octyloxy)calix[4]arene-crown-6 and 1,3-alternate-25,27-bis(3,7-dimethyloctyl-1-oxy)calix[4]arene-benzocrown-6; aq = aqueous phase, org = organic phase) were evaluated. Stability constants of NaL+ and CsL+ were determined from the extraction of picrates and iodides by the solutions of L. Further, the stability constants of the ML+ complexes in nitrobenzene and FS 13 saturated with water were calculated. Enormously high selectivities were found in the systems under study.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
N - Vyzkumna aktivita podporovana z neverejnych zdroju
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Solution Chemistry
ISSN
0095-9782
e-ISSN
1572-8927
Volume of the periodical
49
Issue of the periodical within the volume
12
Country of publishing house
US - UNITED STATES
Number of pages
13
Pages from-to
1497-1509
UT code for WoS article
000584335500001
EID of the result in the Scopus database
2-s2.0-85094872780