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Synergistic extraction of some divalent cations into nitrobenzene by using dicarbollylcobaltate and substituted calix 5 arenes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46356088%3A_____%2F24%3AN0000021" target="_blank" >RIV/46356088:_____/24:N0000021 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22340/24:43930133

  • Result on the web

    <a href="https://www.degruyterbrill.com/document/doi/10.1515/ract-2024-0305/html" target="_blank" >https://www.degruyterbrill.com/document/doi/10.1515/ract-2024-0305/html</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1515/ract-2024-0305" target="_blank" >10.1515/ract-2024-0305</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synergistic extraction of some divalent cations into nitrobenzene by using dicarbollylcobaltate and substituted calix 5 arenes

  • Original language description

    From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibriums Sr2+ (aq) + 2 picrate (aq) + L (nb) double left right arrow SrL2+ (nb) + 2 picrate (nb) and M2+ (aq) + SrL2+ (nb) double left right arrow ML2+ (nb) + Sr2+ (aq) taking place in the two-phase water-nitrobenzene system (M2+ = Ca2+, Ba2+, Pb2+, Cu2+, Zn2+, Cd2+, Mn2+, Co2+, Ni2+, UO22+; L = substituted calix[5]arenes; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Moreover, the stability constants of the ML2+ complexes in nitrobenzene saturated with water were calculated. Very high stability constants of pentaethyl p-tert-butylcalix[5]arene pentaacetate ligand with Ba2+ cation has been found.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    N - Vyzkumna aktivita podporovana z neverejnych zdroju

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Radiochimica Acta

  • ISSN

    0033-8230

  • e-ISSN

    2193-3405

  • Volume of the periodical

    112

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    6

  • Pages from-to

    965-970

  • UT code for WoS article

    001317860400001

  • EID of the result in the Scopus database

    2-s2.0-85205288025