New Polyamide 6 Nanofibrous Sorbents Produced Via Alternating Current Electrospinning For The On-Line Solid Phase Extraction Of Small Molecules In Chromatography Systems

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24410%2F22%3A00009225" target="_blank" >RIV/46747885:24410/22:00009225 - isvavai.cz</a>

Alternative codes found

RIV/00216208:11160/22:10450621

Result on the web

<a href="https://api.elsevier.com/content/article/eid/1-s2.0-S0026265X2101170X" target="_blank" >https://api.elsevier.com/content/article/eid/1-s2.0-S0026265X2101170X</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.microc.2021.107084" target="_blank" >10.1016/j.microc.2021.107084</a>

Result language

angličtina

Original language name

New Polyamide 6 Nanofibrous Sorbents Produced Via Alternating Current Electrospinning For The On-Line Solid Phase Extraction Of Small Molecules In Chromatography Systems

Original language description

Nanofibrous materials provide a large extraction capacity owing to their unique structure. Although most research conducted to date has employed nanofibers produced via the direct current (DC) electrospinning method, the resulting nanofibers have disadvantages that limit their practical use. We focused on the investigation of the electrospinning method using alternating current (AC), firstly used for production of the nanofibrous material as sorbent for extraction. The applicability of the new material was reported as a case study for extraction of bisphenol A (BPA), bisphenol S (BPS), butylparaben (BTP), and fenoxycarb (FXC) in high pressure liquid chromatography system. The nanofibrous samples were produced from polyamide 6 (PA 6) by AC electrospinning. The properties of AC electrospun PA 6 material were compared to the nanofibers produced from the same polymer via conventional DC electrospinning. Our results demonstrated the unique ratio of high porosity, fiber diameter, and specific surface area of AC PA 6 material that led to very good stability in high-pressure flow system and absence of undesired flow and back pressure fluctuations. Good repeatability of cartridge packing with RSD 5.22% for AC material and 16.61 % for DC material, and high extraction efficiency ranging from 95 to 145% was achieved. Efficient on-line extraction procedure enabled the limits of detection ranging from 30 to 60 μg L⁻¹ using both nanofibrous materials and UV detector. The slopes of matrix matched calibration curves demonstrated good selectivity of both extraction materials for BPA, BPS, and BTP. We confirmed the usefulness of our novel approach to nanofiber sorbents for SPE that met the exacting demands in the field of advanced flow extraction methods.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10406 - Analytical chemistry

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2022

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Microchemical Journal

ISSN

0026-265X

e-ISSN

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Volume of the periodical

174

Issue of the periodical within the volume

107084

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

10

Pages from-to

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UT code for WoS article

000736676400008

EID of the result in the Scopus database

2-s2.0-85121778402