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Complexation in the Cu(II)?LiCl?H2O system at temperatures to 423 K by UV-Visible spectroscopy

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24510%2F10%3A%230000187" target="_blank" >RIV/46747885:24510/10:#0000187 - isvavai.cz</a>

  • Alternative codes found

    RIV/46747885:24220/10:#0001578

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Complexation in the Cu(II)?LiCl?H2O system at temperatures to 423 K by UV-Visible spectroscopy

  • Original language description

    Thermodynamic data for the solubility and formation of copper(I)and copper(II) species are required to model innovative designs of the electrolysis cells used in the thermochemical copper-chloride hydrogen production process. Cumulative formation constants of Cu2+(aq) complexes with Cl- (aq) were determined by Principal Component Analysis of UV-spectra, obtained over a very wide range of solution compositions and temperature, coupled with an appropriate model for activity coefficients of the solution species. Shortcomings in the existing database and future work to extend these studies to higher temperatures and much higher copper concentrations are discussed.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/1M0554" target="_blank" >1M0554: Advanced Remedial Technologies and Processes</a><br>

  • Continuities

    V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    International Journal of Hydrogen Energy

  • ISSN

    0360-3199

  • e-ISSN

  • Volume of the periodical

    2010

  • Issue of the periodical within the volume

    35

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    8

  • Pages from-to

  • UT code for WoS article

    278418700045

  • EID of the result in the Scopus database