Complexation in the Cu(II)?LiCl?H2O system at temperatures to 423 K by UV-Visible spectroscopy
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24510%2F10%3A%230000187" target="_blank" >RIV/46747885:24510/10:#0000187 - isvavai.cz</a>
Alternative codes found
RIV/46747885:24220/10:#0001578
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Complexation in the Cu(II)?LiCl?H2O system at temperatures to 423 K by UV-Visible spectroscopy
Original language description
Thermodynamic data for the solubility and formation of copper(I)and copper(II) species are required to model innovative designs of the electrolysis cells used in the thermochemical copper-chloride hydrogen production process. Cumulative formation constants of Cu2+(aq) complexes with Cl- (aq) were determined by Principal Component Analysis of UV-spectra, obtained over a very wide range of solution compositions and temperature, coupled with an appropriate model for activity coefficients of the solution species. Shortcomings in the existing database and future work to extend these studies to higher temperatures and much higher copper concentrations are discussed.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/1M0554" target="_blank" >1M0554: Advanced Remedial Technologies and Processes</a><br>
Continuities
V - Vyzkumna aktivita podporovana z jinych verejnych zdroju
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
International Journal of Hydrogen Energy
ISSN
0360-3199
e-ISSN
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Volume of the periodical
2010
Issue of the periodical within the volume
35
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
8
Pages from-to
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UT code for WoS article
278418700045
EID of the result in the Scopus database
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