Construction of Novel Electro-Fenton Systems by Magnetically Decorating Zero-Valent Iron onto RuO2-IrO2/Ti Electrode for Highly Efficient Pharmaceutical Wastewater Treatment
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24620%2F22%3A00010700" target="_blank" >RIV/46747885:24620/22:00010700 - isvavai.cz</a>
Result on the web
<a href="https://www.mdpi.com/2073-4441/14/7/1044" target="_blank" >https://www.mdpi.com/2073-4441/14/7/1044</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/w14071044" target="_blank" >10.3390/w14071044</a>
Alternative languages
Result language
angličtina
Original language name
Construction of Novel Electro-Fenton Systems by Magnetically Decorating Zero-Valent Iron onto RuO2-IrO2/Ti Electrode for Highly Efficient Pharmaceutical Wastewater Treatment
Original language description
The Electro-Fenton (E-Fenton) technique has shown great potential in wastewater treatment, while the sustainable and continuing supply of Fe2( ) remains challenging. Herein, we demonstrate the construction of a novel E-Fenton system by magnetically decorating zero-valent iron (ZVI) onto a RuO2-IrO2/Ti (ZVI-RuO2-IrO2/Ti) electrode for high-efficient treatment of pharmaceutical wastewater, which is considerably refractory and harmful to conventional biological processes. By using ZVI as a durable source of Fe(II) irons, 78.69% of COD and 76.40% of TOC may be rapidly removed by the developed ZVI-RuO2-IrO2/Ti electrode, while the ZVI-RuO2-IrO2/Ti electrode using ZVI only reduces 35.64% of COD under optimized conditions at initial COD and TOC values of 5500 mg/L and 4300 mg/L, respectively. Moreover, the increase in BOD5/COD from 0.21 to 0.52 highlights the enhanced biodegradability of the treated effluent. The analysis of a simultaneously formed precipitation on electrodes suggests that the coagulation process dominated by Fe3 /Fe2 also plays a non-negligible role in pharmaceutical wastewater treatment. In addition, the monitoring of the evolution of nitrogen elements and the formation of by-products in the E-Fenton process verifies its great capacity toward those organic pollutants found in pharmaceutical wastewater. Our study offers a practical solution for enhancing the performance of E-Fenton systems, and effectively treating refractory pharmaceutical wastewater.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10511 - Environmental sciences (social aspects to be 5.7)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Water
ISSN
2073-4441
e-ISSN
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Volume of the periodical
14
Issue of the periodical within the volume
7
Country of publishing house
CH - SWITZERLAND
Number of pages
19
Pages from-to
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UT code for WoS article
000781093700001
EID of the result in the Scopus database
2-s2.0-85127928328