An efficient sequential method for enhanced landfill leachate treatment and detoxification: Electrocoagulation/permanganate, peroxymonosulfate-based process, and electro-peroxone

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24620%2F25%3A00014120" target="_blank" >RIV/46747885:24620/25:00014120 - isvavai.cz</a>

Result on the web

<a href="https://doi.org/10.1016/j.jenvman.2025.125785" target="_blank" >https://doi.org/10.1016/j.jenvman.2025.125785</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jenvman.2025.125785" target="_blank" >10.1016/j.jenvman.2025.125785</a>

Result language

angličtina

Original language name

An efficient sequential method for enhanced landfill leachate treatment and detoxification: Electrocoagulation/permanganate, peroxymonosulfate-based process, and electro-peroxone

Original language description

This study investigates the electrocoagulation/permanganate (EC/PM) process as a pre-treatment, followed by UV-activated peroxymonosulfate (PMS) and electro-peroxone (EP) treatments. This sequence is designed to effectively mineralize organic matter. Notably, PM was integrated into the EC process for the first time to enhance removal efficiency. The iron sludge generated from the EC/PM process (sludge-derived electrocoagulation; SDEC) was repurposed as a cost-effective source of iron oxide in the PMS/SDEC/UV treatment. Treatment optimization was achieved by adjusting the main operating parameters. A comprehensive analysis was conducted to assess the biodegradability and toxicity of the leachate post-treatment, including measurements of COD, BOD, TOC, ammonia levels, average oxidation state, biodegradability, organic carbon content, and spectroscopic methods. The results demonstrated substantial removal efficiencies across the treatment stages, with 98.9 % for COD, 94.9 % for BOD, 96.4 % for TOC, and 97.7 % for ammonia. Spectroscopic changes indicated that the leachate was broken down into smaller, more oxidized, and highly acidic molecules with an increased aliphatic structure while effectively eliminating aromatic compounds. The BOD5/COD ratio improved to 0.55, indicating that the treated leachate is suitable for biological treatment processes with significantly reduced toxicity. Overall, the sequence of treatment processes yielded promising results.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10511 - Environmental sciences (social aspects to be 5.7)

Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2025

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Environmental Management>

ISSN

0301-4797

e-ISSN

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Volume of the periodical

388

Issue of the periodical within the volume

JUL

Country of publishing house

GB - UNITED KINGDOM

Number of pages

14

Pages from-to

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UT code for WoS article

001500320900002

EID of the result in the Scopus database

2-s2.0-105005945714