A combined experimental and theoretical study on the complexation of H3O+ with hexaethyl calix[6]arene hexaacetate

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23520%2F07%3A00000073" target="_blank" >RIV/49777513:23520/07:00000073 - isvavai.cz</a>

Result on the web

—

DOI - Digital Object Identifier

—

Result language

angličtina

Original language name

A combined experimental and theoretical study on the complexation of H3O+ with hexaethyl calix[6]arene hexaacetate

Original language description

Using the corresponding exchange extraction constant determined in the water-nitrobenzene system, the stability constant of the hydroxonium-substituted calix[6]arene complex in nitrobenzene saturated with water was calculated. Further, by means of DFT method the structure of this complex was derived.

Czech name

Kombinované experimentální a teoretické studium komplexace hydroxoniového kationtu s hexaethyl kalix[6]aren hexaacetátem

Czech description

Pomocí výměnné extrakční konstanty stanovené v systému voda-nitrobenzen byla vypočtena konstanta stability komplexu hydroxonia se substituovaným kalix[6]arenem v nitrobenzenu nasyceném vodou. Metodou DFT byla dále odvozena struktura tohoto komplexu.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CB - Analytical chemistry, separation

OECD FORD branch

—

Project

—

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2007

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Zeitschrift für Physikalische Chemie

ISSN

0942-9352

e-ISSN

—

Volume of the periodical

—

Issue of the periodical within the volume

—

Country of publishing house

DE - GERMANY

Number of pages

7

Pages from-to

519

UT code for WoS article

—

EID of the result in the Scopus database

—