Is the original Kissinger equation obsolete today: not obsolete the entire non-isothermal kinetics?
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23640%2F14%3A43924273" target="_blank" >RIV/49777513:23640/14:43924273 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s10973-014-3810-7" target="_blank" >http://dx.doi.org/10.1007/s10973-014-3810-7</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10973-014-3810-7" target="_blank" >10.1007/s10973-014-3810-7</a>
Alternative languages
Result language
angličtina
Original language name
Is the original Kissinger equation obsolete today: not obsolete the entire non-isothermal kinetics?
Original language description
Physical meaning of activation energy is analyzed from the viewpoint of non-isothermal kinetic evaluation. The term of heat inertia, meaning the degree of slowness with which the temperature of a body approaches that of its surroundings, is examined, andits impact on activation energy determination is discussed, which is particularly functional for a DTA peak kinetic appraisal. Impact of a process equilibrium background on kinetics is recollected as specifically important for Kissinger kinetic evaluation distinguishing competent case of glass cold crystallization on heating but unsuitable for melt crystallization on cooling without introducing additional thermodynamic terms. Parallel to non-Arrhenian kind of kinetics, an analogous model-free description is advocated accentuating a generalized approach by logistic functions.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BJ - Thermodynamics
OECD FORD branch
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Result continuities
Project
<a href="/en/project/ED2.1.00%2F03.0088" target="_blank" >ED2.1.00/03.0088: Centre of the New Technologies and Materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Thermal Analysis and Calorimetry
ISSN
1388-6150
e-ISSN
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Volume of the periodical
117
Issue of the periodical within the volume
1
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
5
Pages from-to
3-7
UT code for WoS article
000338120100002
EID of the result in the Scopus database
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