Kinetic Phase Diagrams as an Enforced Consequence of Rapid Changing Temperature or Diminishing Particle Size: Thermodynamic Fundamentals and Limits
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23640%2F17%3A43950533" target="_blank" >RIV/49777513:23640/17:43950533 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/978-3-319-45899-1_5" target="_blank" >http://dx.doi.org/10.1007/978-3-319-45899-1_5</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/978-3-319-45899-1_5" target="_blank" >10.1007/978-3-319-45899-1_5</a>
Alternative languages
Result language
angličtina
Original language name
Kinetic Phase Diagrams as an Enforced Consequence of Rapid Changing Temperature or Diminishing Particle Size: Thermodynamic Fundamentals and Limits
Original language description
The innovative sphere of kinetic phase diagrams as a special domain of routine thermodynamic determined diagrams is re-evaluated while accentuating its specificity and practical impact when studying system under rapid changes of temperature (e.g., cooling). Requirement for a certain driving force in order to accomplish transformations is explored. It involves merger of heating–cooling as a nonequilibrium thermodynamic state of a certain sample ‘autonomy.’ The meaning of temperature is discussed when measured during inconstant thermal experiments. Thermodynamic legitimacy when assuming the effect of programmed temperature changes at the constant heating rate is examined and approved. Query about the implication of the term ‘temperature’ under rapid quenching results in a proposal of new tem ‘tempericity.’ Size as another degree of thermodynamic freedom is observed and investigated for the issue of nanomaterials providing the apparent analogy between the temperaturedependent kinetic phase diagrams and those obtained for diminishing particle size. Specific behavior of nanocomposites is explored regarding the particle curvature, temperatures of transformation, dissolution or phase separation, etc. Extension of kinetic phase diagram to the nanostate determinability, involving thermodynamics expanded by ‘one dimension’ as a result of severely contracted particle surface, is dealt with. The chapter contains 92 references.
Czech name
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Czech description
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Classification
Type
C - Chapter in a specialist book
CEP classification
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OECD FORD branch
20303 - Thermodynamics
Result continuities
Project
<a href="/en/project/LO1402" target="_blank" >LO1402: CENTEM+</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Book/collection name
Thermal Physics and Thermal Analysis
ISBN
978-3-319-45897-7
Number of pages of the result
22
Pages from-to
109-130
Number of pages of the book
567
Publisher name
Springer International Publishing
Place of publication
Cham, Switzerland
UT code for WoS chapter
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