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Optimization of hydrogen purification from biomass-derived syngas via water gas shift reaction integrated with vacuum pressure swing adsorption for energy storage

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60076658%3A12220%2F24%3A43908927" target="_blank" >RIV/60076658:12220/24:43908927 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1002/est2.604" target="_blank" >https://doi.org/10.1002/est2.604</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/est2.604" target="_blank" >10.1002/est2.604</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Optimization of hydrogen purification from biomass-derived syngas via water gas shift reaction integrated with vacuum pressure swing adsorption for energy storage

  • Original language description

    Biomass is one of the promising sources to produce green H2, which can be considered an energy storage medium. To produce high-purity H2 from biomass-derived syngas, this study implemented a two-stage H2 purification process. In the first stage, a water gas shift reaction (WGSR) was performed to enhance the H2 concentration in the syngas. The Taguchi method was employed to analyze the influence of the operating conditions and maximize the H2 concentration in the water gas shift reaction product. The results suggested that reaction temperature is a more dominant factor for enhancing the H2 concentration than the molar steam/carbon monoxide (S/CO) ratio. In the second stage, vacuum pressure swing adsorption was employed to obtain the high-concentration H2 using the product from the water gas shift reaction having the optimum H2 concentration. Using the adsorption pressure as the primary parameter, it was found that high H2 purity and recovery could be obtained from vacuum pressure swing adsorption operated at low adsorption pressures. Based on this study&apos;s results, the vacuum pressure swing adsorption unit&apos;s best outcome occurs during an adsorption pressure of 2 kg center dot cm-2 and a flow rate of 17 L center dot min-1. Under these conditions, 93.61% H2 purity, 31.63% H2 recovery, 4.86 mol H2 center dot(kgads center dot h)-1 productivity, and 448.14 kJ center dot(kg H2)-1 energy consumption are obtained. image

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    40500 - Other agricultural sciences

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Energy Storage

  • ISSN

    2578-4862

  • e-ISSN

    2578-4862

  • Volume of the periodical

    6

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

    1-11

  • UT code for WoS article

    001182126300001

  • EID of the result in the Scopus database