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Electronic Structure of 1,3-dicarbomethoxy4,6-benzenedicarboxylic acid: Density Functional Approach

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60076658%3A12520%2F13%3A43885136" target="_blank" >RIV/60076658:12520/13:43885136 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Electronic Structure of 1,3-dicarbomethoxy4,6-benzenedicarboxylic acid: Density Functional Approach

  • Original language description

    Structural optimization of 1,3-dicarbomethoxy4,6-benzenedicarboxylic acid single crystal was performed by minimizing the forces which act on the atoms. The optimized geometry was used to perform the theoretical study of electronic properties, electroniccharge density and optical properties. Electronic structure, electronic charge density and optical properties were investigated using the full potential linear augmented plane wave based on the first-principles density functional theory (DFT). The exchange correlation (XC) effects are taken in to account by Local Density Approximation (LDA), Generalized Gradient Approximation (GGA) and modified Becke Johnson (MBJ) potential. The band structure shows that the calculated compound has an indirect band gapof 2.99, 3.05 and 3.93 eV for LDA, GGA and mBJ respectively. The electron charge densities were also analyzed and discussed. The charge densities indicate that bonding between H-O, C-C and O-O is mainly covalent and the bonding between O

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/ED2.1.00%2F01.0024" target="_blank" >ED2.1.00/01.0024: South Bohemian Research Center of Aquaculture and Biodiversity of Hydrocenoses</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE

  • ISSN

    1452-3981

  • e-ISSN

  • Volume of the periodical

    8

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    RS - THE REPUBLIC OF SERBIA

  • Number of pages

    17

  • Pages from-to

    10359-10375

  • UT code for WoS article

    000323548600019

  • EID of the result in the Scopus database