LC-HRMS method for study of pharmaceutical uptake in plants: effect of pH under aeroponic condition
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60076658%3A12520%2F23%3A43906608" target="_blank" >RIV/60076658:12520/23:43906608 - isvavai.cz</a>
Alternative codes found
RIV/60460709:41210/23:95675
Result on the web
<a href="https://doi.org/10.1007/s11356-023-29035-1" target="_blank" >https://doi.org/10.1007/s11356-023-29035-1</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11356-023-29035-1" target="_blank" >10.1007/s11356-023-29035-1</a>
Alternative languages
Result language
angličtina
Original language name
LC-HRMS method for study of pharmaceutical uptake in plants: effect of pH under aeroponic condition
Original language description
Global climate changes cause water scarcity in many regions, and the sustainable use of recycled water appears crucial, especially in agriculture. However, potentially hazardous compounds such as pharmaceuticals can enter the food chain and pose severe risks. This paper aims to study the presence of selected pharmaceutical active compounds (PhACs) and their metabolites in crops grown in aeroponic conditions and evaluate the potential of PhAC plant uptake. A solvent extraction with an acidified mixture of acetonitrile and water followed by LC-HRMS was developed and validated for quantifying nine pharmaceuticals and their nine metabolites in three plants. We aimed for a robust method with a wide linear range because an extensive concentration range in different matrices was expected. The developed method proved rapid and reliable determination of selected pharmaceuticals in plants in the wide concentration range of 10 to 20,000 ng g(-1) and limit of detection range 0.4 to 9.0 ng g(-1). The developed method was used to study the uptake and translocation of pharmaceuticals and their metabolites in plant tissues from an aeroponic experiment at three different pH levels. Carbamazepine accumulated more in the leaves of spinach than in arugula. On the other hand, sulfamethoxazole and clindamycin evinced higher accumulation in roots than in leaves, comparable in both plants. The expected effect of pH on plants' uptake was not significant.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Environmental Science and Pollution Research
ISSN
0944-1344
e-ISSN
1614-7499
Volume of the periodical
30
Issue of the periodical within the volume
42
Country of publishing house
DE - GERMANY
Number of pages
12
Pages from-to
96219-96230
UT code for WoS article
001047320500008
EID of the result in the Scopus database
2-s2.0-85167797122